| Purpose - |
This demonstration shows the effect of oxidation on
the pH of a liquid. |
The colourless stage of
the Fading Blue Solution

....and the blue stage!!
|
| Nature - |
Demonstration |
| Materials - |
conical or round bottom
flask, stopper, 200ml distilled water, 5g potassium hydroxide, 3 gm
glucose, 10 -12 drops of methylene blue |
| Method - |
- Mix ingredients in flask and
stopper
- Give flask a good shake to mix.
Solution should be a blue colour (similar to copper sulphate
solution).
- Let stand for a few minutes and you
should find the solution goes colourless again. Give it a
shake to return it to blue, and let it sit and fade again.
- Repeat several times.
|
| Safety - |
Standard precautions when
using chemicals |
| Explanation - |
When you shake the flask it
forces more oxygen to dissolve into the mixture, which is involved
in an oxidation reaction. This reduces the pH and causes the
methylene blue to go blue. After a sitting for a while some of
the oxygen comes back out of solution, raising the ph again, and the
methylene blue goes to colourless. |
| Notes - |
This
solution must be made fresh just before use as it breaks down over a
few hours.
Upon
each subsequent shaking, the blue will be weaker in colour and will
last for less time. |
|